I have used just about everything for my sleeves, except delrin. The only thing delrin gets used for in my shop, is glue clamp blocks. I just find them to soft, to slick and nothing sticks to it. (Perfect for a glue block)
As for the other materials, I have never cut grooves in my sleeves. I make sure it's not shiny, so at most I scuff them with sand paper. I've never had a problem.
As for ebonite, I love the feel and look of it. However, after years of "NOT" wearing a respirator, because it just smells a little like sulfer, I now have an have a reaction to that smell. It burns a lot more than it smells, coming out the other end (for a couple of days). Even if I wear a respirator, it any dust lingering in the shop or on my clothes will have the same effect. So now I only have a couple of small pieces left, and it's only used under special request.