Probably the easiest way to tell the difference between the two "common" types of plastic are:
Acrylic will be square, with no visible chips, it is often very shiny.
Acrylestor is a polyester resin and often has noticable chips out of the edges, they appear to be very similar to when I windshield gets a chip. It also tends to be dual when in blank form.
Acrylic will not chip when dropped on a hard surface, where acrylester will.