- CA (Cyanoacrylate) Finish
- Why it works: CA glue cures through a chemical reaction, not evaporation, and is less affected by humidity (though extremely high humidity can accelerate curing).
- Tips:
- Use thin coats to avoid fogging.
- Work quickly; high humidity can cause it to set faster than expected.
- Consider a dehumidifier or small fan nearby to help regulate conditions.
This one is interesting... CA cures through a cascade reaction that is most often triggered by water reacting with the initial chemicals of CA that form the polymers. Water molecules have that polarity, which causes this weak double bond on the reactive end of the individual polymer molecules to break, forming a single bond and freeing up an electron to bond with the water (or rather OH). Once that initial bond is broken, it changes the polarity of the entire molecule, which then allows it to do the same thing to other molecules of the polymer, kicking off a chain reaction. A tiny bit of water can actually trigger the formation of long polymer chains in CA. Once the process is kicked off, it tends to accelerate, and its exothermic, thus the way it spits off fumes as it releases the materials of its medium (which are solvents and thickeners, usually.)
I had heard in the past that 75% was basically the cutoff point for applying CA, but that in general with higher humidity, it would usually start to polymerize faster because there is more readily available water in the air to kick off the process. So the open time is shorter, at the very least, but then the chance of clouding increases progressively as well.
I have been working on pens again (after some time not), and a short while back we had some rain storms move through. While I did not get clouding, I did leave a blank on the lathe overnight after I had applied the final coats. In the morning, the entire surface had a frosty white appearance. I suspect it was because of the humidity overnight (we had heavy rains)...and I wonder, if I had actively been applying CA later that night, if I would have ended up with cloudiness. I think the humidity topped out at around 60%, and I wasn't even sure what I was looking at at first...it looked like a thin layer of frost.