Hi
A copper based alloy is best such as copper or brass, dont use stainless or mild etc as that will increase your processes as they will need to be copper plated, nickel plated, then rep chrome plated.
First of allm forget chrome plating get that completely out of your mind. its extremely dangerous and definately not to be done at home. a drop of the chemical going down your sink or toilet etc will trigger alarms at your local waterworks. if you have ever seen the film Erin Brocovich where all the people in the town were dieing of cancer, its because hexevalent chromium was seeping from a nearby factory into the waterworks. nasty stuff.
The good news is, there are platings which look very close to chrome. certainly close enough so you wont tell the difference. sure if you were to put it aside a car at a show with all ts bright polished chrome you may not have that ultra high mirror finish as the car, but youl be close.
In an ideal world you should tank plate to increase its durability as it will give you a thicker coating. however this will exceed your budget. brush plating would be the way forward, though remember that just because the piece has turned rep chrome, that doesnt mean you are done. that will take a minute or so, but you really need to keep brushing the piece for at least 20 minutes so you can build up a thicker coat so it doesnt wear as much with use. i suggest you put some music on while your doing it because so much as 10 minutes in you will be bored out of your mind.
Take a look here for a kit.
Plug N' Plate® Copy Chrome Kit - Plug N' Plate® Brush Plating Kits - Caswell Inc
Here is a pen done in this method: