Cutting yourself on a sharp turning tool and only knowing you've cut yourself after you notice a red tinge on the piece your turning. Happened to me the first time in a lot of years just the other day.
Respirator or lack there of. I don't know how many times I've seen videos with people turning all kinds of stuff without using a proper respirator.
Gluing my fingers together.
Locking myself out of the shop and having to climb through a window while trying to avoid the various tools.
I once had a Possum in my shop that took several hours to get to the door and back outside. Boy...they sure look mean.
Distraction while working. I've launched quite a few things across my shop by being distracted.
Having a first aid kit without any of the first aid items inside. Doesn't do any good to have a kit if you can't use.
I've done a lot of really dumb stuff that makes great stories but some of them I'll keep to myself.
I think I've done all these, except for locking myself out. Oh, and we don't have possums here in Maine, but we have a bumper crop of squirrels this year. Haven't had one in the shop yet (plenty of mice, though) but I did have one manage to get from the attic into my bedroom. For some reason my wife was amused to see me tape a flashlight to my pellet gun at 1:00 am and proceed to try and ventilate the squirrel with it.