platinum or rhodium cufflinks?

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Yes Dan, you are right. But the investment of platinum is "arguably" negligible. But the notion of gifting platinum is, well, very nice to me! :)
 
In general you don't want to plate over chrome. In most cases I would strip the existing plating prior to Rhodium plating. Here is one system. Keep in mind Rhoduim is NOT CHEAP!

Rhodium Pen Plating System 1 oz - Caswell Inc

Another

http://www.riogrande.com/Product/Midas-Rhodium-Plating-Solutions-Acid-Based/335055

For occasional hobby plating batteries can be used for a power source.

Do your research first. It is really very easy to do. Many of the chemicals are "not nice" but with reasonable care, you should be fine.
 
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